Games I want to be on the Wii's VC:
Donkey Kong Country 1 (SNES) http://en.wikipedia.org/wiki/DKC (apparently this one is available on the VC ?)
Donkey Kong Country 2 (SNES) http://en.wikipedia.org/wiki/DKC2 (aparently this one too?)
Donkey Kong Country 3 (SNES) http://en.wikipedia.org/wiki/DKC3 (...and this one too?)
Earthworm Jim (SNES) http://en.wikipedia.org/wiki/Earthworm_Jim
I own the DK ones and my roommate owns EWJ for the SNES.
I don't really hope to get a whole bunch of them...most of the consoles that you'll be able to download games for, I already own, and if possible, I prefer owning games on their original consoles (unless there's some sort of enhancement =D). Although I guess I'd want rare/hard to find games, like Zelda/lttp, maybe Secret of Mana...hmm...Conkers Bad Fur Day...can't think of much else.
I think I own all the consoles other than NES.
Although if it has Sega Saturn (I doubt it, and yes, I really don't know), I'll want Shinining Force 3, assuming that they have the first episodes in english. It'd be cool if they translated the whole thing too.